This is mostly a “note to self”. If you receive “The database could not be exclusively locked to perform the operation.” error message, you have to put the DB in the single user mode, then change the collation. Here’s how to do it:
USE MASTER GO ALTER DATABASE moovme SET SINGLE_USER WITH ROLLBACK IMMEDIATE ALTER DATABASE moovme COLLATE Slovenian_CI_AS ALTER DATABASE moovme SET MULTI_USER GO
Hope that helps anyone.